Organoaluminum hydrides catalyzed hydroboration of carbonates, esters, carboxylic acids, and carbon dioxide was written by Yan, Ben;Dutta, Sayan;Ma, Xiaoli;Ni, Congjian;Koley, Debasis;Yang, Zhi;Roesky, Herbert W.. And the article was included in Dalton Transactions in 2022.Synthetic Route of C13H10O3 The following contents are mentioned in the article:
Reduction of carbonates, carboxylic acids and ester was achieved in reaction with HBpin and [(nacnac)AlH2] catalyst. The reductive functionalization of the C:O unit of carbonates, carboxylic acids, esters, and CO2, resp. has received great attention since its introduction. This method is often used industrially for the synthesis of high value-added energy products in chem. This opens up a new way forward to reduce greenhouse gases and the consumption of traditional energy sources. Herein, we report an earth-abundant, cheap, and readily available aluminum dihydride, which can catalyze the reduction of a range of carbonates, esters, carboxylic acids, and CO2, resp. in the presence of pinacolborane as a reducing agent. Moreover, we demonstrate that the reaction can proceed to obtain good yield products under mild conditions, with low catalyst loading and solvent-free reactions. The mechanism of the catalytic reduction of carbonates has been investigated. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Synthetic Route of C13H10O3).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Synthetic Route of C13H10O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics