The author of 《Molecular-Scale Interfacial Model for Predicting Electrode Performance in Rechargeable Batteries》 were Ming, Jun; Cao, Zhen; Li, Qian; Wahyudi, Wandi; Wang, Wenxi; Cavallo, Luigi; Park, Kang-Joon; Sun, Yang-Kook; Alshareef, Husam N.. And the article was published in ACS Energy Letters in 2019. Synthetic Route of C3H2O3 The author mentioned the following in the article:
It is commonly believed that the formation of a solid-electrolyte interphase (SEI) is the main reason for improved electrode performance in rechargeable batteries. However, herein we present a new interfacial model that may change the thinking about the role of SEI, which has prevailed over the past 2 decades. We show that the varied desolvation behavior of mobile ions, which depends on the solvation structure determined by multiple factors (e.g., cations, solvent, anions, and additives) is a critical factor for electrode stability besides the SEI. This interfacial model can predict the intercalating species in graphite electrodes (i.e., Li+ (de)intercalation or Li+-solvent co-insertion) in different types of electrolytes (e.g., carbonate-, ether-based electrolyte). The generality of our model is further demonstrated by its ability to interpret the variable lithium plating/stripping in different electrolytes. Our model can predict electrode performance through the proposed cation-solvent interactions and desolvation behaviors and then help develop new types of electrolytes for mobile (ion) batteries. In the part of experimental materials, we found many familiar compounds, such as Vinylene carbonate(cas: 872-36-6Synthetic Route of C3H2O3)
Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Synthetic Route of C3H2O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics