Xiao, Xiong et al. published their research in Journal of the American Chemical Society in 2020 |CAS: 707-07-3

The Article related to triflic anhydride glycosylation glycoside merremoside oligosaccharide thioglycoside, Carbohydrates: Oligosaccharides and other aspects.Safety of (Trimethoxymethyl)benzene

On March 25, 2020, Xiao, Xiong; Zeng, Jing; Fang, Jing; Sun, Jiuchang; Li, Ting; Song, Zejin; Cai, Lei; Wan, Qian published an article.Safety of (Trimethoxymethyl)benzene The title of the article was One-Pot Relay Glycosylation. And the article contained the following:

A novel one-pot relay glycosylation has been established. The protocol is characterized by the construction of two glycosidic bonds with only one equivalent of triflic anhydride. This method capitalizes on the in situ generated cyclic-thiosulfonium ion as the relay activator, which directly activates the newly formed thioglycoside in one pot. A wide range of substrates are well-accommodated to furnish both linear and branched oligosaccharides. The synthetic utility and advantage of this method have been demonstrated by rapid access to naturally occurring phenylethanoid glycoside kankanoside F and resin glycoside merremoside D. The experimental process involved the reaction of (Trimethoxymethyl)benzene(cas: 707-07-3).Safety of (Trimethoxymethyl)benzene

The Article related to triflic anhydride glycosylation glycoside merremoside oligosaccharide thioglycoside, Carbohydrates: Oligosaccharides and other aspects.Safety of (Trimethoxymethyl)benzene

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics