On August 31, 2018, Borys, Filip; Paprocki, Daniel; Koszelewski, Dominik; Ostaszewski, Ryszard published an article.COA of Formula: C10H14O3 The title of the article was The studies on the chemoenzymatic synthesis of 2-benzyl-3-butenoic acid. And the article contained the following:
The studies on the chemoenzymic synthesis of 2-benzyl-3-butenoic acid 3 were performed. The alkylation of dienolates derived from the crotonic and vinylacetic acids with different types of alkylating agents was examined In all cases the inseparable mixture of isomeric acids 3 and 4 were obtained. Chemoselective enzymic esterification of those mixtures provides ester 6 in 86% yield as a single product without double bond isomerization. None common method can be used for its hydrolysis since under basic conditions only isomeric acid 5 is formed. To overcome this limitation enzyme catalyzed hydrolysis process was design. This protocol afforded isomerically pure acid 3 in 98% yield. The experimental process involved the reaction of (Trimethoxymethyl)benzene(cas: 707-07-3).COA of Formula: C10H14O3
The Article related to chemoenzymic synthesis benzyl butenoic acid, Fermentation and Bioindustrial Chemistry: Industrial Chemicals and other aspects.COA of Formula: C10H14O3
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