On September 26, 2018, Fu, Liangbing; Zhang, Tianqi; Fu, Guanyao; Gutekunst, Will R. published an article.Name: 3-Aminodihydrothiophen-2(3H)-one hydrochloride The title of the article was Relay Conjugation of Living Metathesis Polymers. And the article contained the following:
The covalent coupling of complex macromols. is a modern challenge in both chem. and biol. The development of efficient and chemoselective methods for polymer coupling and functionalization are increasingly important for designing new advanced materials and interfacing with biochem. systems. Herein, we present a new strategy to directly conjugate living polymers prepared using ring-opening metathesis polymerization (ROMP) to both small mols. and synthetic macromols. Central to this methodol. is a terminal alkyne that serves as a directing group to promote a rapid, intramol. reaction with an otherwise unreactive olefin. This highly chemoselective relay conjugation is compatible with a range of monomer families and uses a bench-stable enyne motif that can be easily introduced to functional targets. The rapid rate of the conjugation reaction paves the way for greatly streamlined construction of complex macromol. systems derived from metathesis polymerization techniques without the need for specialized equipment. The experimental process involved the reaction of 3-Aminodihydrothiophen-2(3H)-one hydrochloride(cas: 6038-19-3).Name: 3-Aminodihydrothiophen-2(3H)-one hydrochloride
The Article related to relay conjugation living metathesis polymer, Chemistry of Synthetic High Polymers: Ring-Opening and Other Polymerizations and other aspects.Name: 3-Aminodihydrothiophen-2(3H)-one hydrochloride
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