On January 6, 2012, Jacolot, Maiwenn; Jean, Mickael; Levoin, Nicolas; van de Weghe, Pierre published an article.Product Details of 3976-69-0 The title of the article was The Prins Reaction Using Ketones: Rationalization and Application toward the Synthesis of the Portentol Skeleton. And the article contained the following:
We report a TMSI-promoted Prins cyclization reaction with ketones as carbonyl partners to prepare polysubstituted chiral spirotetrahydropyrans. In the presence of racemic 2-methylcyclohexanone a dynamic kinetic resolution occurred affording one stereoisomer. The observed enantiospecificity has been rationalized by DFT calculation The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Product Details of 3976-69-0
The Article related to crystal mol structure nitro oxaspiro undecanyl benzamide, chiral spiropyran portentol skeleton preparation, dft mechanism calculation prins cyclization ketone, Heterocyclic Compounds (One Hetero Atom): Spiro Compounds With One Hetero Atom In Each Ring and other aspects.Product Details of 3976-69-0
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