Miura, Tomoya; Moritani, Shunsuke; Shiratori, Yota; Murakami, Masahiro published an article in 2022, the title of the article was 1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols.Electric Literature of 10472-24-9 And the article contains the following content:
A unique method for the synthesis of substituted 1-naphthols I (R = Ts, Ms, R1 = 6-F, 6-Cl, 7-Me, etc., R2 = Me, CO2Me) by rhodium(II)-catalyzed ring-expansion reaction of 2-triazolyl-1-indanone derivatives II (R3 = 5-F, 5-Cl, 6-Me, etc.) is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Electric Literature of 10472-24-9
The Article related to naphthol preparation, triazolyl indanone ring expansion acyl migration rhodium catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Electric Literature of 10472-24-9
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