On May 10, 2021, Newar, Rajashree; Akhtar, Naved; Antil, Neha; Kumar, Ajay; Shukla, Sakshi; Begum, Wahida; Manna, Kuntal published an article.Reference of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate The title of the article was Amino Acid-Functionalized Metal-Organic Frameworks for Asymmetric Base-Metal Catalysis. And the article contained the following:
The Authors report a strategy to develop heterogeneous single-site enantioselective catalysts based on naturally occurring amino acids and earth-abundant metals for eco-friendly asym. catalysis. The grafting of amino acids within the pores of a metal-organic framework (MOF), followed by post-synthetic metalation with iron precursor, affords highly active and enantioselective (>99% ee for 10 examples) catalysts for hydrosilylation and hydroboration of carbonyl compounds Impressively, the MOF-Fe catalyst displayed high turnover numbers of up to 10 000 and was recycled and reused more than 15 times without diminishing the enantioselectivity. MOF-Fe displayed much higher activity and enantioselectivity than its homogeneous control catalyst, likely due to the formation of robust single-site catalyst in the MOF through site-isolation. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).Reference of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate
The Article related to amino acid functionalized iron metal organic framework preparation catalyst, asym base catalysis hydrosilylation hydroboration carbonyl compound, amino acid, enantioselectivity, heterogeneous catalysis, iron, metal-organic frameworks and other aspects.Reference of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate
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