Martinez-Guillen, Jose R.; Flores-Ferrandiz, Jesus; Gomez, Cecilia; Gomez-Bengoa, Enrique; Chinchilla, Rafael published an article in 2018, the title of the article was Asymmetric conjugate addition of α,α-disubstituted aldehydes to nitroalkenes organocatalyzed by chiral monosalicylamides from trans-cyclohexane-1,2-diamines.Name: Phenyl Salicylate And the article contains the following content:
Primary amine-salicylamides derived from chiral trans-cyclohexane-1,2-diamines are used as organocatalysts for the enantioselective conjugate addition of α,α-disubstituted aldehydes to arylated and heteroarylated nitroalkenes. The reaction is performed in the presence of 4-dimethylaminopyridine as an additive in dichloromethane as a solvent at room temperature The corresponding enantioenriched γ-nitroaldehydes are obtained with enantioselectivities up to 95%. Theor. calculations are used to justify the reasons of the stereoinduction. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Name: Phenyl Salicylate
The Article related to chiral monosalicylamides trans cyclohexane diamine asym conjugate dimethylaminopyridine additive, disubstituted aldehydes nitroalkenes organocatalyst dichloromethane enantioselectivity, michael addition, asymmetric synthesis, nitroalkenes, organocatalysis and other aspects.Name: Phenyl Salicylate
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