Cai, Yuanhong; Tan, Donghang; Zhang, Qiqi; Lv, Wenxin; Li, Qingjiang; Wang, Honggen published the artcile< Synthesis of difluoromethylated benzylborons via rhodium(I)-catalyzed fluorine-retainable hydroboration of gem-difluoroalkenes>, Related Products of 112-63-0, the main research area is rhodium catalyzed fluorine retainable hydroboration gem fluoroalkene; fluoromethylated benzylborane preparation.
The synthesis of borylated organofluorines is of great interest due to their potential values as synthons in modular construction of F-containing mols. Reported herein is a Rh-catalyzed hydroboration of aryl gem-difluoroalkenes leading to α-difluoromethylated benzylborons. The use of cationic Rh catalyst and a biphosphine ligand with large bite angle was crucial for reactivity by offering good regioselectivity and diminishing the undesired β-F elimination. Preliminary derivatizations of the products were conducted to showcase the utility of this protocol.
Chinese Chemical Letters published new progress about Boranes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (difluoromethylated benzylborons). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics