McDonald, Ivar M.; Mate, Robert; Ng, Alicia; Park, Hyunsoo; Olson, Richard E. published the artcile< Novel tricyclic diamines 2. Synthesis of 1,7-diazaisoadamantane, 1,5-diazaisoadamantane and 1,6-diazahomobrendane>, Quality Control of 112-63-0, the main research area is azaisoadamantane synthesis azaindole; azahomobrendane synthesis azaindole; azaindole synthesis tandem Sonogashira coupling intramol cyclization.
Three novel tricyclic diamines (1,7-diazaisoadamantane, 1,5-diazaisoadamantane and 1,6-diazahomobrendane) were prepared (isoadamantane and homobrendane numbering systems are shown as I and II, resp.). A flexible synthetic strategy was employed which used flat, aromatic azaindoles as the starting materials. The requisite azaindoles were prepared by a tandem Sonogashira coupling/intramol. cyclization reaction. Ring saturation, appropriate functionalization and intramol. alkylation provided the three novel tricyclic diamines cores.
Tetrahedron Letters published new progress about Chromatographic chiral resolution (of diazaisoadamantane precursors). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics