Zhu, Bo; Yan, Lin; Pan, Yuanhang; Lee, Richmond; Liu, Hongjun; Han, Zhiqiang; Huang, Kuo-Wei; Tan, Choon-Hong; Jiang, Zhiyong published the artcile< Lewis base catalyzed enantioselective allylic hydroxylation of Morita-Baylis-Hillman carbonates with water>, Electric Literature of 112-63-0, the main research area is alc enantioselective synthesis; Morita Baylis Hillman carbonate allylic hydroxylation Lewis base catalyst.
A Lewis base catalyzed allylic hydroxylation of Morita-Baylis-Hillman (MBH) carbonates has been developed. Various chiral MBH alcs. can be synthesized in high yields (up to 99%) and excellent enantioselectivities (up to 94% ee). This is the first report using water as a nucleophile in asym. organocatalysis. The nucleophilic role of water has been verified using 18O-labeling experiments
Journal of Organic Chemistry published new progress about Allylic alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics