Rickborn, Bruce; Wuesthoff, Michael T. published the artcile< Kinetics, stereochemistry, and mechanism of the sodium borohydride reduction of alkyl-substituted cyclohexanones>, Electric Literature of 112-63-0, the main research area is kinetics reduction cyclohexanones; cyclohexanones reduction kinetics; stereochem reduction cyclohexanones.
The previously used method for determining the kinetics of NaBH4 reduction of cyclohexanones was inadequate, giving rise to small errors leading to measurably low rate constants A AgNO3-ethylenediamine potentiometric method gave correct values as shown by correspondence with the rate constants determined directly by vpc anal. Changes in stereochemistry during the course of reduction were observed with some substituted cyclohexanones, implying a significant buildup of an intermediate borohydride species. The rate constants and stereochem. results are discussed in terms of steric, electronic, and conformational effects.
Journal of the American Chemical Society published new progress about Reduction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics