Bouayad-Gervais, Samir; Nielsen, Christian D.-T.; Turksoy, Abdurrahman; Sperger, Theresa; Deckers, Kristina; Schoenebeck, Franziska published the artcile< Access to Cyclic N-Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides>, Name: 4-tert-Butylphenylisothiocyanate, the main research area is cyclic trifluoromethyl urea preparation; carbamoyl azide potocatalytic activation.
Mild activation of carbamoyl azides to the corresponding nitrenes using a blue light/[Ir]-catalyzed strategy, which enabled stereospecific access to N-trifluoromethyl imidazolidinones and benzimidazolones was reported. These novel structural motifs proved to be highly robust, allowing their downstream diversification. On the basis of combined computational and exptl. studies, it was proposed that an electron rebound with the excited metal catalyst was undergone, involving a reduction-triggered nitrogen loss, followed by oxidation to the corresponding carbamoyl nitrene and subsequent C-H functionalization.
Journal of the American Chemical Society published new progress about Amides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 19241-24-8 belongs to class esters-buliding-blocks, and the molecular formula is C11H13NS, Name: 4-tert-Butylphenylisothiocyanate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics