Beccalli, Egle M.; Bernasconi, Alice; Borsini, Elena; Broggini, Gianluigi; Rigamonti, Micol; Zecchi, Gaetano published the artcile< Tunable Pd-Catalyzed Cyclization of Indole-2-carboxylic Acid Allenamides: Carboamination vs Microwave-Assisted Hydroamination>, Application of C19H34O2, the main research area is vinyl imidazoindole preparation; indolecarboxylic acid allenamide preparation carboamination hydroamination palladium catalyst.
A variety of 3-vinyl-substituted imidazo[1,5-a]indole derivatives were synthesized by intramol. Pd-catalyzed cyclization of the title allenamides through either a domino carbopalladation/exo-cyclization process or a novel hydroamination reaction that proceeds smoothly under microwave irradiation Both observed pathways involve a π-allyl-palladium(II) complex arising from insertion of the allene group into a palladium(II) species, the latter being formed in situ by the intervention of an aryl iodide or of the N-H group. In both cases, the role of nucleophile is covered by the indole nitrogen.
Journal of Organic Chemistry published new progress about Allenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (allenamides). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics