Jiang, Minbao; Yuan, Yong; Wang, Tao; Xiong, Yunkui; Li, Jun; Guo, Huijiao; Lei, Aiwen published the artcile< Exogenous-oxidant- and catalyst-free electrochemical deoxygenative C2 sulfonylation of quinoline N-oxides>, Electric Literature of 112-63-0, the main research area is sulfonylated quinoline regioselective green preparation; quinoline oxide sodium sulfinate electrochem deoxygenative sulfonylation.
An exogenous-oxidant- and catalyst-free electrochem. deoxygenative C2 sulfonylation reaction was achieved. By employing quinoline N-oxides with sodium sulfinates as the starting materials, the electrochem. C-H sulfonylation of electron-deficient quinolines was indirectly achieved at room temperature and a variety of sulfonylated quinoline derivatives I [R = Et, Ph, 4-ClC6H4, etc.; R1 = H, 3-Me, 6-Br, etc.] were synthesized in modest to high yield with excellent regioselectivity. Notably, this protocol was the first example for synthesizing sulfonylated electron-deficient heteroarenes/arenes through electrochem.
Chemical Communications (Cambridge, United Kingdom) published new progress about Amine oxides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
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Ester – an overview | ScienceDirect Topics