Salehi Marzijarani, Nastaran; Lam, Yu-hong; Wang, Xiao; Klapars, Artis; Qi, Ji; Song, Zhiyan; Sherry, Benjamin D.; Liu, Zhijian; Ji, Yining published the artcile< New Mechanism for Cinchona Alkaloid-Catalysis Allows for an Efficient Thiophosphorylation Reaction>, Application of C19H34O2, the main research area is nucleoside thiophosphorylation cinchona alkaloid catalysis mechanism.
An efficient synthesis of nucleoside 5′-monothiophosphates under mild reaction conditions using com. available thiophosphoryl chloride was achieved with a cinchona alkaloid catalyst. A detailed mechanistic study of the reaction was undertaken, employing a combination of reaction kinetics, NMR spectroscopy, and computational modeling, to better understand the observed reactivity. Taken collectively, the results support an unprecedented mechanism for this class of organocatalyst.
Journal of the American Chemical Society published new progress about Cinchona alkaloids Role: CAT (Catalyst Use), RCT (Reactant), SPN (Synthetic Preparation), USES (Uses), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics