Minhas, Harsimran K’s team published research in Organic & Biomolecular Chemistry in 2018 | 112-63-0

Organic & Biomolecular Chemistry published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.

Minhas, Harsimran K.; Riley, William; Stuart, Alison M.; Urbonaite, Martyna published the artcile< Activation of the hypervalent fluoroiodane reagent by hydrogen bonding to hexafluoroisopropanol>, COA of Formula: C19H34O2, the main research area is dicarbonyl compound hypervalent fluoroiodane fluorination; fluoro dicarbonyl compound preparation; alkenyl carboxylic acid hypervalent fluoroiodane regioselective fluorocyclization; fluorolactone preparation.

Hexafluoroisopropan-2-ol (HFIP) is an excellent solvent for promoting fluorinations with the hypervalent fluoroiodane and crucially, it removes the need for transition metals or TREAT-HF activators. The fluoroiodane reagent was used in HFIP to monofluorinate 1,3-carbonyl compounds and to fluorocyclize unsaturated carboxylic acids in excellent yields under mild reaction conditions.

Organic & Biomolecular Chemistry published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics