Takemura, Naho; Sumida, Yuto; Ohmiya, Hirohisa published the artcile< Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate>, Related Products of 112-63-0, the main research area is silyl radical generation method silylboronate light driven; three component reaction silyl radical acylimidazole alkene photocatalysis; acylsilane derivative radical preparation heterocyclic carbene photocatalysis.
A visible-light-driven silyl radical generation method from silylboronates was developed. The activation of silylboronates with a catalytic amount of mild base promoted the single-electron oxidation process to form silyl radicals. Facile single electron transfer for the borate form readily occurred without H atom transfer for hydrosilane in the presence of various photoredox catalysts. Combining this protocol with radical-mediated N-heterocyclic carbene catalysis enabled the acylsilylation of alkenes via a radical relay process with silyl radical generation. Also, the recent advanced methods for the synthesis of silylboronates significantly improved the utility of this silyl radical generation alkenes acylimidazole.
ACS Catalysis published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics