Iwasaki, Masayuki; Iino, Shohei; Nishihara, Yasushi published the artcile< Palladium-Catalyzed Annulation of o-Iodobiphenyls with o-Bromobenzyl Alcohols: Synthesis of Functionalized Triphenylenes via C-C and C-H Bond Cleavages>, Application of C19H34O2, the main research area is palladium phosphine catalyzed annulation iodobiphenyl bromobenzyl alc triphenylene; decarbonylative cross coupling intramol cyclization triphenylene synthesis.
Treatment of o-iodobiphenyls with o-bromobenzyl alcs. in the presence of cesium carbonate under palladium catalysis affords a series of highly substituted triphenylenes [e.g., o-iodobiphenyl + 2-(2-bromophenyl)-2-propanol in presence of PdCl2(NCPh)2/P[3,5-(CF3)2C6H3]3 and Cs2CO3 afforded triphenylene in 81% yield].. The reaction involves two C-C bond formations and C-C and C-H bond cleavages. A combination of palladium and an electron-deficient phosphine ligand proves to be effective for both decarbonylative cross-coupling and intramol. cyclization.
Organic Letters published new progress about Aralkyl alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics