Braun, Manfred; Devant, Ralf published the artcile< The (R)- and (S)-2-acetoxy-1,1,2-triphenylethanols - effective synthetic equivalents of a chiral acetate enolate>, Formula: C19H34O2, the main research area is aldehyde addition enolate stereochem; acetoxytriphenylethanol chiral acetate equivalent; carboxylic acid hydroxy.
The enolate I, easily available by double deprotonation of (R)-AcOCHPhCPh2OH, adds in a highly stereoselective manner to aldehydes RCHO (R = Ph, Me2CH, Pr). Hydrolysis of the adducts II and III affords the acids IV.
Tetrahedron Letters published new progress about Addition reaction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics