Guo, Xin; Basu, Kallol; Cabral, Jose A.; Paquette, Leo A. published the artcile< Relative Rate Profile for Ring-Closing Metathesis of a Series of 1-Substituted 1,7-Octadienes as Promoted by a 4,5-Dihydroimidazol-2-ylidene-Coordinated Ruthenium Catalyst>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is ruthenium imidazolylidene catalyzed ring closing metathesis octadiene Hammett analysis.
This report details the kinetic responses of nine compounds of type 6 [RCH:CH(CH2)2CH(OCH2Ph)CH2CH:CH2] to ring-closing metathesis as promoted by Grubbs’ Ru-dihydroimidazolylidene catalyst to give the identical product 7 [4-(benzyloxy)cyclohexene]. The exptl. observations have been subjected to Hammett anal. The ρ value for the composite aromatic derivatives (R = p-XC6H4-) differs from that of the aliphatic series, although both are neg. because electron-donating groups accelerate the reaction.
Organic Letters published new progress about Alkadienes Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics