Emmanuvel, Lourdusamy; Shaikh, Tanveer Mahammad Ali; Sudalai, Arumugam published the artcile< NaIO4/LiBr-mediated Diastereoselective Dihydroxylation of Olefins: A Catalytic Approach to the Prevost-Woodward Reaction>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is dihydroxylation stereoselective alkene oxidant lithium bromide; diol stereoselective synthesis; Prevost Woodward reaction dihydroxylation sodium periodate lithium bromide; green chem metal free stereoselective dihydroxylation Prevost Woodward reaction.
LiBr catalyzes efficiently the dihydroxylation of alkenes to afford syn and anti diols with excellent diastereoselectivity depending upon the use of NaIO4 (30 mol %) or PhI(OAc)2 (1 equiv), resp., as the oxidizing agents. The oxidation of non-benzylic halides has been achieved for the first time to afford the corresponding diols in excellent yields.
Organic Letters published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics