Devi, Jai; Kothari, Seema; Banerji, Kalyan K. published the artcile< Kinetics and mechanism of oxidation of some α-amino acids by pyridinium hydrobromide perbromide>, COA of Formula: C19H34O2, the main research area is kinetics mechanism oxidation amino acid; pyridinium hydrobromide perbromide oxidation.
Oxidation of nine α-amino acids by pyridinium hydrobromide perbromide (PHPB) in aqueous acetic acid leads to the formation of the corresponding aldehydes. The reaction is first order with respect to PHPB. Michaelis-Menten type kinetics are observed with respect to some of the amino acids while other amino acids exhibit a second order dependence. The oxidation of perdeuterioglycine showed the absence of a kinetic isotope effect. The effect of solvent composition indicates that the reaction rate increases with an increase in the polarity of the medium. Addition of pyridinium hydrobromide and bromide ion have no effect on the rate of oxidation The reaction is susceptible to both polar and steric effects of the substituents. It failed to induce polymerization of acrylonitrile. Suitable mechanisms have been proposed.
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry published new progress about Amino acids Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics