Zhang, Wenzhi; Bie, Fusheng; Ma, Jie; Zhou, Fengyan; Szostak, Michal; Liu, Chengwei published the artcile< Palladium-Catalyzed Decarbonylative Borylation of Aryl Anhydrides>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is palladium catalyzed decarbonylative borylation aryl anhydride; arylboronate ester preparation.
A Pd-catalyzed base-free decarbonylative borylation of aryl anhydrides was developed. Catalyst system consisting of Pd(OAc)2/dppb enables readily available aryl anhydrides to be employed as electrophiles for the synthesis of versatile arylboronate esters via O-C(O) bond activation and decarbonylation. This method was characterized by an excellent functional group tolerance and broad substrate scope, using bench stable aryl anhydrides as aryl electrophiles in C-B bond formation. Mechanistic studies and functionalization of late-stage pharmaceutical mols. are disclosed.
Journal of Organic Chemistry published new progress about Anhydrides, aryl Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics