McErlean, Christopher S. P.; Willis, Anthony C. published the artcile< Application of an intramolecular Stetter reaction to access trans,syn,trans-fused pyrans>, Computed Properties of 112-63-0, the main research area is trans syn fused bicyclic pyranone preparation; crystal structure trans syn fused bicyclic pyranon.
The use of a com. available thiazolium salt facilitated an intramol. Stetter reaction between an aliphatic aldehyde and an acrylate unit, which delivered a trans,syn-fused bicyclic pyranone in high yield as a single diastereomer. The pyranone was used to synthesize a trans,syn,trans-fused polycyclic ether array and was ring expanded to give the corresponding oxepanone.
Synlett published new progress about Aliphatic aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics