Suarez-Pantiga, Samuel; Hernandez-Ruiz, Raquel; Virumbrales, Cintia; Pedrosa, Maria R.; Sanz, Roberto published the artcile< Reductive Molybdenum-Catalyzed Direct Amination of Boronic Acids with Nitro Compounds>, Reference of 112-63-0, the main research area is aromatic amine chemoselective preparation; boronic acid nitro compound reductive amination molybdenum catalyst; amination; boronic acids; molybdenum; nitro compounds; reduction.
A practical and efficient procedure for the synthesis of secondary aromatic amines RNHR1 [R = Me, i-Pr, Ph, etc.; R1 = n-Bu, Ph, 2-naphthyl, etc.] was reported via a direct amination of boronic acids with nitro compounds The novel combination of a dioxomolybdenum(VI) catalyst and triphenylphosphine as inexpensive reductant had revealed to be decisive to achieve this new C-N coupling. Our methodol. was proved to be scalable, air and moisture tolerant, highly chemoselective and engages both aliphatic and aromatic nitro compounds Moreover, this general and step-economical synthesis of secondary aromatic amines showcased orthogonality to other aromatic amine syntheses as it tolerated aryl halides and carbonyl compounds
Angewandte Chemie, International Edition published new progress about Aromatic amines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
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Ester – an overview | ScienceDirect Topics