Becker, Heinrich; Soler, Marcos A.; Sharpless, K. Barry published the artcile< Selective asymmetric dihydroxylation of polyenes>, Category: esters-buliding-blocks, the main research area is asym dihydroxylation polyene; hydroxylation di asym polyene; stereochem dihydroxylation polyene; olefin poly asym dihydroxylation; osmylation asym polyene.
The asym. dihydroxylation procedure (AD) is applied to a variety of polyenes. In many cases excellent regioselectivities are obtained. The observed selectivities are rationalized in terms of electronic and/or steric effects inherent to the substrate, superimposed on the substrate’s favorable or unfavorable interactions with the binding pocket of the AD ligand. Surprisingly, for medium and large ring olefins with trans-double bonds outstanding enantioselectivities are realized using the pyrimidine ligands. A hexaol of D3 symmetry is prepared from all trans cyclododecatriene.
Tetrahedron published new progress about Alkenes, polyene alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics