Mathur, Dipti; Sharma, Pradeep K.; Banerji, Kalyan K. published the artcile< Kinetics and mechanism of oxidation of primary alcohols by pyridinium hydrobromide perbromide>, Electric Literature of 112-63-0, the main research area is oxidation primary alc pyridinium hydrobromide perbromide; kinetics mechanism oxidation primary alc; LFER Winstein Grunwald Pavelich Taft.
Oxidation of nine primary aliphatic alcs. by pyridinium hydrobromide perbromide (PHPB) in aqueous acetic acid leads to the formation of the corresponding aldehydes. The reaction is first order with respect to PHPB. Michaelis-Menten-type kinetics are observed with respect to the alc. The oxidation of MeCD2OH exhibits a substantial kinetic isotopic effect. The effect of solvent composition indicates that the transition state is more polar than the reactions. The reaction is susceptible to both polar and steric effects of the substituents. A mechanism involving transfer of a hydride ion from the alc. to the oxidant has been proposed.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics