Fukuyama, Takahide; Bando, Takanobu; Ryu, Ilhyong published the artcile< Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams>, Electric Literature of 112-63-0, the main research area is benzolactone benzolactam preparation; benzyl alc amine carbon monoxide intramol Heck carbonylation.
A metal-catalyst-free intramol. Heck carbonylation reaction of benzyl alcs. and benzyl amines with carbon monoxide under heating at 250é?affords the corresponding benzolactones and benzolactams in good to excellent yields. A hybrid radical/ionic chain mechanism, involving electron transfer from radical anions generated by nucleophilic attack of alcs. or amines on intermediate acyl radicals, is proposed.
Synthesis published new progress about Aralkyl alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics