Kovtunenko, V A’s team published research in Khimiya Geterotsiklicheskikh Soedinenii in 1988-07-31 | 112-63-0

Khimiya Geterotsiklicheskikh Soedinenii published new progress about Cyclocondensation reaction, intramolecular. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.

Kovtunenko, V. A.; Kisel, V. M.; Tyltin, A. K.; Babichev, F. S. published the artcile< Novel approach to the synthesis of dibenz[b,f]azocine system>, Formula: C19H34O2, the main research area is dibenzazocine acetylcyanohydroxydihydro preparation IR; cyanomethylbenzylanthranilate preparation acetylation; acetylcyanomethylbenzylanthranilate preparation cyclocondensation.

Alkylating o-H2NC6H4CO2Et with o-BrCH2C6H4CH2CN in Me2CHOH containing NaOAc gave 54% o-NCCH2C6H4CH2NRC6H4CO2Et-o (I; R = H), which was acetylated with AcCl in dry dioxane containing Et3N to give 94% I (R = Ac). Intramol. cyclocondensation reaction of the latter on heating in Me3COH containing KOCMe3 gave 73% title derivative II, the IR spectrum of which showed no keto tautomer either in the solid state or in DMSO solution

Khimiya Geterotsiklicheskikh Soedinenii published new progress about Cyclocondensation reaction, intramolecular. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics