Lowe, Gordon; Potter, Barry V. L. published the artcile< Synthesis, absolute configuration, and circular dichroism of the enantiomers of fluorosuccinic acid>, Reference of 617-55-0, the main research area is malate ester stereospecific fluorination; fluorosuccinate configuration CD; succinate fluoro configuration CD; asym preparation fluorosuccinate.
D-labeling showed that fluorination of (2S)- and (2R)-MeO2CCH(OH)CH2CO2Me with Et2NSF3 (CHCl3, 0é?ambient temperature) occurred stereospecifically with inversion of configuration to give (2R)- and (2S)-MeO2CCHFCH2CO2Me, resp., (I, II, resp.). The CD spectra of I and II and the corresponding acids, obtained by acid hydrolysis, were ‘anomalous’, showing that the previously determined (Harper, D. B., Blakeley, E. R.; 1971) absolute configuration of (+)-HO2CCHFCH2CO2H obtained from Pseudomonal is incorrect.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about Circular dichroism. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Reference of 617-55-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics