Chen, Xiao Yun; Bohmann, Rebekka Anna; Wang, Long; Dong, Shunxi; Raeuber, Christoph; Bolm, Carsten published the artcile< Palladium/Copper-Cocatalyzed Oxidative Amidobrominations of Alkenes>, Safety of Perfluorophenyl acrylate, the main research area is sulfoxime vinyl preparation; acrylate sulfoximine oxidative amidobromination palladium copper cocatalysis; C閳ユ弲 bond formation; C閳ユ彉 bond formation; copper cocatalysis; dehydrogenative amidobromination; palladium catalysis.
In the presence of LiBr, a palladium/copper combination catalyzes dehydrogenative amidobrominations of acrylates with NH-sulfoximines, leading to N-vinylated products by dual NH/CH coupling, followed by oxidative enamide bromination. Mechanistically, the domino process is proposed to involve palladium(II) species as key intermediates. First synthetic applications of the products have been demonstrated.
Chemistry – A European Journal published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, Safety of Perfluorophenyl acrylate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics