Frogley, Benjamin J.; Wright, L. James published the artcile< A Metallaanthracene and Derived Metallaanthraquinone>, Product Details of C19H34O2, the main research area is crystal structure mol metallaanthracene metallaanthraquinone derivative preparation reactivity; cyclization; fused-ring metallabenzene; iridium; metallaanthracene; metallacycles.
Metalla-analogs of archetypal aromatic mols. are attracting ever increasing interest. Although metallabenzenes (which fall within this class) have been well studied, fused-ring metallabenzenes are rare and of the linear polycyclic metallaarom. hydrocarbons, only metallanaphthalene is known. Herein we report the first metallaanthracene, [Ir(C13H8{CH2CO2Me-5})Cl(PPh3)2]O3SCF3 (5), which represents the next member of this series of polycyclic compounds Structurally, 5 has a number of features in common with anthracene including fused-ring planarity and bond-length alternation. In analogs of classic reactions of anthracene, 5 forms a Diels-Alder adduct with maleic anhydride and on oxidation the unprecedented fused-ring metallaanthraquinone, [Ir(C15H6O{Br-6}{OMe-7}{:O-8}{:O-15})Br(PPh3)2], is obtained.
Angewandte Chemie, International Edition published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics