Geary, Gemma C.; Hope, Eric G.; Singh, Kuldip; Stuart, Alison M. published the artcile< Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is hypervalent iodine fluoride preparation electrophilic fluorination reagent; keto ester electrophilic fluorination hypervalent iodine fluoride; diketone electrophilic fluorination hypervalent iodine fluoride.
The air- and moisture-stable fluoroiodane I, readily prepared on a 6 g scale by nucleophilic fluorination of the corresponding hydroxyiodane with TREAT-HF, was used as an electrophilic fluorinating reagent to monofluorinate 1,3-keto esters and difluorinate 1,3-diketones with good isolated yields.
Chemical Communications (Cambridge, United Kingdom) published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics