Palo-Nieto, Carlos; Sau, Abhijit; Galan, M. Carmen published the artcile< Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals>, Safety of (2R,3R,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate, the main research area is deoxyglycoside stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether; oligosaccharide stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether; glycosyl amino acid stereoselective synthesis gold catalyzed hydrofunctionalization glycal; glycoconjugate stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether.
Au(I) in combination with AgOTf enables the unprecedented direct and ä¼?stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of the enol ether glycoside. The room temperature reaction is high yielding and amenable to a wide range of glycal donors and OH nucleophiles.
Journal of the American Chemical Society published new progress about Amino acids Role: SPN (Synthetic Preparation), PREP (Preparation) (glycosyl). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Safety of (2R,3R,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics