Hang, Wei; Yi, Yaping; Xi, Chanjuan published an article in Advanced Synthesis & Catalysis. The title of the article was 《Cobalt-Catalyzed Reductive Carboxylation of Aryl Bromides with Carbon Dioxide》.HPLC of Formula: 1877-71-0 The author mentioned the following in the article:
Cobalt-catalyzed reductive carboxylation of aryl bromides with carbon dioxide to form the corresponding carboxylic acids ArC(O)OH [Ar = Ph, 4-MeOC6H4, 1-naphthyl, etc.] in good to high yields was developed. The reaction proceeded under one atm pressure of CO2 at 40°C in the presence of cobalt iodide/2,2′-bipyridine catalysts and zinc dust as a reducing reagent. Preliminary mechanistic experiments ruled out intervention of intermediate organozinc species for carboxylation with CO2, thus suggested direct CO2 insertion into the corresponding ArCoBr species. In addition to this study using 3-(Methoxycarbonyl)benzoic acid, there are many other studies that have used 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0HPLC of Formula: 1877-71-0) was used in this study.
3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters.HPLC of Formula: 1877-71-0 They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics