Geiselhart, Christina M.; Mutlu, Hatice; Tzvetkova, Pavleta; Barner-Kowollik, Christopher published the artcile< Chemiluminescent self-reporting supramolecular transformations on macromolecular scaffolds>, Computed Properties of 71195-85-2, the main research area is macromol scaffold chemiluminescent self reporting supramol transformation.
We introduce the synthesis of a self-reporting system with chemiluminescent output, which is regulated via dynamic supramol. complex formation. By free radical polymerization and subsequent post-polymerization modification, a copolymer decorated with luminol and superbase (i.e. 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD)) moieties was synthesized, which in turn forms supramol. host-guest-complexation with randomly methylated β-cyclodextrin. Upon hydrogen peroxide addition, the host-guest-interactions with the self-assembly are broken, and the luminol is oxidized to 3-aminophthalic acid (3-APA). Critically, no addnl. base, buffer or catalyst is required to generate the striking blue light emission of the polymeric system that is detectable by the naked eye. Thus, a fast and easy detection of reactive oxygen species (ROS), such as hydrogen peroxide, under mild conditions is established. The self-reporting system and its chemiluminescent properties are characterized by 1D and 2D NMR spectroscopy (particularly NOESY), dynamic light scattering (DLS), UV/Vis spectroscopy and chemiluminescence (CL) measurements.
Polymer Chemistry published new progress about Chemiluminescence. 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, Computed Properties of 71195-85-2.
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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics