Jozsef, Janos; Juhasz, Laszlo; Somsak, Laszlo published the artcile< Thio-click reaction of 2-deoxy-exo-glycals towards new glycomimetics: stereoselective synthesis of C-2-deoxy-D-glycopyranosyl compounds>, COA of Formula: C12H16O7, the main research area is deoxyglycal Bamford Stevens deoxyglycopyranosylmethyl sulfide disaccharide; configuration deoxyglycopyranosyl cyanide anhydroaldose tosylhydrazone reduction tosylhydrazine.
A series of 2-deoxy-glycopyranosyl cyanides with D-arabino, D-lyxo, D-erythro, and D-threo configurations was synthesized from the corresponding glycals via 2-deoxy-glycopyranosyl acetates. The cyanides were transformed to anhydro-aldose tosyl-hydrazones by reduction with NaH2PO2/Ra-Ni in the presence of tosylhydrazine. The tosyl-hydrazones furnished 2-deoxy-exo-glycals under modified Bamford-Stevens conditions. Photo-initiated thiol-ene additions of these exo-glycals resulted in the corresponding C-(2-deoxy-D-glycopyranosyl)methyl sulfides in medium to good yields with exclusive regio- and stereoselectivities in most cases. Several disaccharide mimics with a C-S moiety in place of the glycosidic oxygen were also obtained.
New Journal of Chemistry published new progress about Aldoses Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, COA of Formula: C12H16O7.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics