Himmelstrup, Jonas; Buendia, Mikkel B.; Sun, Xing-Wen; Kramer, Soeren published the artcile< Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is chiral binuclear gold complex preparation; enantioselective aryl coupling arylbornic acid binuclear gold catalyst.
Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp2)-C(sp2) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.
Chemical Communications (Cambridge, United Kingdom) published new progress about Atropisomers. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics