He, Tao; Liu, Li-Chuan; Ma, Wen-Peng; Li, Bin; Zhang, Qing-Wei; He, Wei published the artcile< Enantioselective Construction of Si-Stereogenic Center via Rhodium-Catalyzed Intermolecular Hydrosilylation of Alkene>, HPLC of Formula: 112-63-0, the main research area is dihydrosilane desymmetrization hydrosilylation allyl ether preparation chiral silane; rhodium BINAP BIPHEP catalyst enantioselective hydrosilylation allyl ether; Si-stereogenic center; alkenes; desymmetrization; hydrosilylation; rhodium.
Catalytic, enantioselective synthesis of Si-stereogenic silicon compounds ArSiEt(H)(CH2)3OR (Ar = 2,6-Cl2C6H3, R = aryl) was achieved by desymmetrization of dihydrosilanes ArSiEt(H)2 by hydrosilylation of allyl ethers catalyzed by rhodium BINAP- or BIPHEP-type catalysts. The reaction is regioselective, producing linear silanes with moderate enantioselectivities. This new method features a simple catalytic system, mild reaction conditions and a wide functional group tolerance.
Chemistry – A European Journal published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, HPLC of Formula: 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics