Smith, J. R.; Campbell, S. A.; Ratcliffe, N. M.; Dunleavy, M. published the artcile< Polyheterocycles containing alkene spacer linkages. Part I. Synthesis and electropolymerization of 3-styrylthiophenes>, Reference of 112-63-0, the main research area is thickness electrode deposited polystyrylthiophene film; indium tin electrode deposited polystyrylthiophene; platinum electrode deposited polystyrylthiophene; porosity electrodeposited polystyrylthiophene film; poorly conducting polystyrylthiophene film synthesis; supporting electrolyte styrylthiophene electrochem polymerization; Hammett sigma constant styrylthiophene electrooxidation; elec potential substituted styrylthiophene oxidation; cyclic voltammogram substituted styrylthiophene.
The synthesis and electrochem. behavior of novel thiophene compounds containing a substituted Ph group separated by an alkene spacer are described. In such systems, it was proposed that the mol. geometry should allow the π-electron d. of the Ph group to be delocalized with that of the thiophene ring by means of the alkene spacer. The presence of this unsaturated linkage should also minimize steric hindrance between the two rings. A number of such monomers exhibiting a range of electronic effects were prepared and their electrochem. behavior investigated. Although films were deposited on the anode surface by electropolymerization, the conductivities were of the order of 10-6 S cm-1. The nature of the films was investigated by electrochem. and microscopic techniques. Potentiodynamic studies indicated that the alkene spacer linkage may be subject to irreversible electrooxidation Polymer redox peaks, characteristic of anion mobility within conductive polymers, were absent from the cyclic voltammograms. SEM observations showed that the films were exceptionally smooth and homogeneous.
Synthetic Metals published new progress about Electric conductivity. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
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