In 2017,Rajendiran, Senkuttuvan; Park, Kwangho; Lee, Kwangyeol; Yoon, Sungho published 《Ionic-Liquid-Based Heterogeneous Covalent Triazine Framework Cobalt Catalyst for the Direct Synthesis of Methyl 3-Hydroxybutyrate from Propylene Oxide》.Inorganic Chemistry published the findings.Computed Properties of C4H8O3 The information in the text is summarized as follows:
β-Hydroxy esters are considered as potential building blocks for the production of fine chems. and potential drug mols. in various industries. Developing an efficient and recyclable catalyst for the synthesis of β-hydroxy esters is challenging. Here we report the first ionic-liquid-based heterogenized cobalt catalyst, [imidazolium-CTF][Co(CO)4], for the direct ring-opening carbonylation of propylene oxide to Me 3-hydroxybutyrate (MHB) with 86% selectivity (>99% conversion). In addition to this study using Methyl 3-hydroxypropanoate, there are many other studies that have used Methyl 3-hydroxypropanoate(cas: 6149-41-3Computed Properties of C4H8O3) was used in this study.
Methyl 3-hydroxypropanoate(cas: 6149-41-3) belongs to esters with low molecular weight are commonly used as fragrances and found in essential oils and pheromones. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Computed Properties of C4H8O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics