The author of 《Palladium-Catalyzed Synthesis of Indolines from Aroyloxycarbamates through a Tandem Decarboxylative Amination/Heck/Annulation Reaction》 were Wang, Zheng; Li, Peihe; Fu, Hui; Dai, Qipu; Hu, Changwen. And the article was published in Advanced Synthesis & Catalysis in 2019. Product Details of 36016-38-3 The author mentioned the following in the article:
A novel synthesis of functionalized indolines via a Pd-catalyzed tandem decarboxylative amination/Heck/annulation reaction has been developed. This process features operational simplicity, mild conditions, and the use of a readily available and environmentally friendly starting material, namely carboxylic acid. Furthermore, the reaction shows good functional group tolerance and chem. selectivity.N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3Product Details of 36016-38-3) was used in this study.
N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3) belongs to anime. Amines have a free lone pair with which they can coordinate to metal centers. Amine–metal bonds are weaker because amines are incapable of backbonding, but they are still important for sensing applications.While stronger than hydrogen bonds, amine–metal bonds are still weaker than both covalent and ionic bonds.Product Details of 36016-38-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics