Subramanian, Kripa; Yedage, Subhash L.; Bhanage, Bhalchandra M. published the artcile< Electrodimerization of N-alkoxyamides for zinc(II) catalyzed phenolic ester synthesis under mild reaction conditions>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is phenolic ester preparation; alkoxyamide phenol electrodimerization coupling zinc catalyst.
The one-pot protocol began with rapid and selective electrodimerization of the amide using n-Bu4NI (TBAI) as an electrocatalyst. The reaction proceeded further in the absence of current via Zn catalyzed C-N bond activation of the amide dimer followed by its coupling with phenol to form the phenolic esters I [R = 4-Me, 2,4-di-F, 2-MeO, etc.; R1 = Et, Ph, 4-ClC6H4, etc.]. The present methodol. was ligand-free and took place under mild reaction conditions. This transformation incorporated a wide variety of phenols and amide substrates leading to the formation of functionalized esters highlighting its versatility.
Advanced Synthesis & Catalysis published new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (alkoxy). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics