Moitessier, Nicolas; Chretien, Francoise; Chapleur, Yves published the artcile< Asymmetric dihydroxylation of D-xylose-derived allyl ethers>, COA of Formula: C19H34O2, the main research area is stereochem hydroxylation xyloside ether; allylxyloside asym dihydroxylation AD mix.
The catalytic asym. dihydroxylation of several allyl 2-O-benzyl-α-D-xylosides with AD-mix β and PYR(DHQD)2 shows poor diastereofacial selectivity if the 3- and 4-OH groups are unprotected or acetylated. Acetal, benzyl ethers and benzoyl esters enhance the diastereoselectivity which is opposite to that predicted by the “”AD mnemonic”” and which is completely lost using AD-mix α.
Tetrahedron: Asymmetry published new progress about Hydroxylation (asym., di-). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics