Huang, Pei-Qiang; Lan, Hong-Qiao; Zheng, Xiao; Ruan, Yuan-Ping published the artcile< A Concise Asymmetric Synthesis of (2S,3S,7S)-3,7-Dimethylpentadecan-2-yl Acetate and Propionate, the Sex Pheromones of Pine Sawflies>, Formula: C6H10O5, the main research area is dimethylpentadecanyl acetate propionate asym synthesis pine sawfly sex pheromone; pentadecanyl acetate propionate dimethyl asym synthesis pine sawfly pheromone; chemoselective regioselective stereoselective ester reduction epoxidation dimethylpentadecanyl acetate propionate; epoxide opening chemoselective regioselective stereoselective dimethylpentadecanyl acetate propionate synthesis.
(2S,3S,7S)-3,7-Dimethylpentadecan-2-yl acetate (I) and its propionate analog (II) are the main sex pheromones of all Neodiprion species and Diprion similes, resp. Starting from (S)-malic acid and employing a highly chemo-, regio-, and stereoselective tandem ester reduction-epoxide formation-reductive epoxide-opening reaction protocol, an efficient total synthesis of (2S,3S,7S)-I and II is reported herein.
Journal of Organic Chemistry published new progress about Reduction. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Formula: C6H10O5.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics