Ma, Xiantao; Xu, Qing; Li, Huan; Su, Chenliang; Yu, Lei; Zhang, Xu; Cao, Hongen; Han, Li-Biao published the artcile< Alcohol-based Michaelis-Arbuzov reaction: an efficient and environmentally-benign method for C-P(O) bond formation>, Electric Literature of 112-63-0, the main research area is Michaelis Arbuzov green alc carbon phosphorus bond formation; phosphonate phosphinate phosphine oxide preparation.
The famous Michaelis-Arbuzov reaction is extensively used both in the laboratory and industry to manufacture tons of widely-used organophosphoryl compounds every year. However, this method and the modified Michaelis-Arbuzov reactions developed recently still have some limitations. We now report a new alc.-version of the Michaelis-Arbuzov reaction that can provide an efficient and environmentally-benign method to address the problems of the known Michaelis-Arbuzov reactions. That is, a wide range of alcs. can readily react with phosphites, phosphonites, and phosphinites to give all the three kinds of phosphoryl compounds (phosphonates, phosphinates, and phosphine oxides) using an n-Bu4NI-catalyzed efficient C-P(O) bond formation reaction. This general method can also be easily scaled up and used for further synthetic transformations in one pot.
Green Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics