Darbem, Mariana P.; Esteves, Henrique A.; de Oliveira, Isadora M.; Pimenta, Daniel C.; Stefani, Helio A. published the artcile< Palladium-Catalyzed Thio- and Selenocarbonylation of 2-Iodoglycals>, Synthetic Route of 4098-06-0, the main research area is glycoside thioester selenoester catalytic thiocarbonylation coupling monosaccharide; thiol iodoglycal cross coupling molybdenum hexacarbonyl carbon monoxide disaccharide.
The carbonylative cross-coupling reactions of 2-iodoglycals with thiols and selenols in the presence of molybdenum hexacarbonyl as a solid source of carbon monoxide is described. This methodol. permitted the synthesis of 29 C2-glycosides bearing thioester and selenoester functionalities in moderate to excellent yields and high functional group tolerance. Moreover, this communication describes the first catalytic carbonylative coupling reaction of selenols with a carbon electrophile.
ChemCatChem published new progress about Carbonylation. 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Synthetic Route of 4098-06-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics