Das, Anindita; Lin, Shaojian; Theato, Patrick published the artcile< Supramolecularly Cross-Linked Nanogel by Merocyanine Pendent Copolymer>, Electric Literature of 71195-85-2, the main research area is supramolecularly crosslinked nanogel merocyanine pendent polyacrylic.
Directional dipole-dipole interaction mediated antiparallel dimerization of merocyanine dye (MD) has been explored for maneuvering supramol. assembly of MD-conjugated flexible macromols. leading to a cross-linked nanogel. The MD-functionalized copolymer was synthesized by a newly developed organocatalytic transesterification strategy for postpolymn. functionalization of poly(pentafluorophenyl acrylate) (polyPFPA)-based reactive copolymer. Presence of ∼35% pendant MD attached to a coil-like polymer chain leads to spontaneous formation of highly emitting crosslinked nanogel with efficient container property and appreciable stability in toluene owing to strong dimerization propensity among the MD. Considering the significance of MD in the context of nonlinear optics and photovoltaics, these results not only enrich the toolbox for engineering macromol. assembly, but also open up new possibilities for future organic materials.
ACS Macro Letters published new progress about Fluoropolymers Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, Electric Literature of 71195-85-2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics